Month: April 2025

Alex and Kyle gave the oral presentation in TMS 2025 (Las Vegas)!

Alex and Kyle gave the oral presentation in TMS 2025 (Las Vegas)!

Kyle Wade (former MS. Student): Microstructural and micro-mechanical characterization of isothermally heat-treated  Al6061 cold spray deposit

Alex Horvath (PhD student): A Large Hysteresis Behavior in CaFe2As2 Single Crystals via the Bauschinger Effect associated with Buckling-Induced Formation of Nanocrystalline Structure

Shuyang’s collaboration paper was published at Physical Review B!

Shuyang’s collaboration paper was published at Physical Review B! Congratulations!

https://journals.aps.org/prb/abstract/10.1103/PhysRevB.111.054102

Title: Tuning the structure and superconductivity of SrNi2P2  by Rh substitution

Abstract: The compound SrNi2⁢P2 is unique among the ThCr2⁢Si2 class since it exhibits a temperature-induced transition upon cooling from an uncollapsed tetragonal (ucT) state to a one-third-collapsed orthorhombic (tcO) state where one out of every three P-rows bond across the Sr layers. This compound is also known for exhibiting bulk superconductivity below 1.4 K at ambient pressure. In this paper, we report on the effects of Rh substitution in Sr⁢(Ni1−⁢Rh)2⁢P2 on the structural and superconducting properties. We studied the variation of the nearest P-P distances as a function of the Rh fraction at room temperature, as well as its temperature dependence for selected compositions. We find that increasing the Rh fraction leads to a decrease in the transition temperature between the ucT and tcO states, until a full suppression of the tcO state for ≥0.166. The superconducting transition first remains nearly insensitive to the Rh fraction, and then it increases to 2.3 K after the tcO state is fully suppressed. These results are summarized in a phase diagram, built upon the characterization by energy dispersive x-ray spectroscopy, x-ray diffraction, resistance, magnetization, and specific heat measurements done on crystalline samples with varying Rh content. The relationship between band structure, crystal structure, and superconductivity is discussed based on previously reported band structure calculations on SrRh2⁢P2. Moreover, the effect of Rh fraction on the stress-induced structural transitions is also addressed by means of strain-stress studies done by uniaxial compression of single-crystalline micropillars of Sr⁢(Ni1−⁢Rh)2⁢P2.